Corrosion for Science and Engineering 2nd ed2025|PDF|Epub|mobi|kindle电子书版本百度云盘下载

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1 Corrosion and society1

1.1 The lessons of history1

1.2 The expense of corrosion5

1.3 Social implications of corrosion8

1.4 Corrosion and the environment17

1.5 Concluding remarks19

1.6 References19

1.7 Bibliography21

2 Enabling theory for aqueous corrosion23

2.1 Energy: the rule of law23

2.2 Matters of substance26

2.3 Processes in solution31

2.4 Metals: might and blight34

2.5 Metals in the melting pot35

2.6 Defects in metal structures37

2.7 Electrical science39

2.8 Glossary44

2.9 Worked examples45

2.10 Problems47

2.11 Bibliography48

3 Practical aqueous corrosion49

3.1 Common apparatus49

3.2 The experiments51

3.3 Discussion65

4 The theory of aqueous corrosion69

4.1 Thermodynamics of corrosion reactions71

4.2 The basic wet corrosion cell75

4.3 Standard electrode potentials81

4.4 Reference electrodes85

4.5 Cell potential87

4.6 Kinetics of corrosion reactions91

4.7 Polarisation95

4.8 Diffusion processes and the double layer100

4.9 Mixed potential theory102

4.10 Pourbaix diagrams106

4.11 Three-electrode cells and E/lg i plots111

4.12 Polarisation curves120

4.13 Electrochemical impedance124

4.14 References128

4.15 Bibliography129

5 Dissimilar metal corrosion130

5.1 The galvanic series135

5.2 Corrosion quantification139

5.3 References143

5.4 Bibliography143

6 Selective attack144

6.1 Grain boundary corrosion145

6.2 Intergranular corrosion147

6.3 Selective leaching151

6.4 Microbiologically induced corrosion156

6.5 References160

6.6 Bibliography160

7 Crevice and pitting corrosion: concentration cells162

7.1 The mechanism of crevice corrosion165

7.2 Pitting corrosion168

7.3 Differential-aeration corrosion169

7.4 Electrochemical techniques173

7.5 Material susceptibility186

7.6 References187

7.7 Bibliography190

8 Flow-induced corrosion191

8.1 Fluid flow191

8.2 Cavitation196

8.3 Bibliography197

9 Enabling theory for environment-sensitive cracking199

9.1 Elasticity: stress and strain199

9.2 The tensile test201

9.3 Stress concentration203

9.4 Linear elastic fracture mechanics205

9.5 Fatigue209

9.6 Bibliography213

10 Environment-sensitive cracking214

10.1 Stress-corrosion cracking218

10.2 Environment-sensitive cracking: initiation221

10.3 Environment-sensitive cracking: propagation223

10.4 Environment-sensitive cracking: practical aspects228

10.5 Corrosion fatigue231

10.6 References237

10.7 Bibliography239

11 Corrosion management240

11.1 Corrosion control242

11.2 Primary and secondary corrosion mechanisms243

11.3 The people factor248

11.4 Knowledge-based systems251

11.5 Concluding remarks254

11.6 References254

11.7 Bibliography255

12 Corrosion control by design256

12.1 How long do I expect it to last?257

12.2 The ever-changing environment259

12.3 Minimise bimetallic corrosion cells261

12.4 Avoid differential-aeration cells264

12.5 Tanks and pipe systems270

12.6 Stray current corrosion273

12.7 References277

12.8 Bibliography278

13 Corrosion control by environmental change279

13.1 Atmospheric corrosion280

13.2 Control of atmospheric corrosion282

13.3 Modification of the electrolyte286

13.4 Control of aqueous environments294

13.5 Soil as an environment299

13.6 References300

13.7 Bibliography301

14 Corrosion control by coatings302

14.1 Paint systems304

14.2 Paint characteristics306

14.3 Paint types308

14.4 Paint failure319

14.5 Painting costs322

14.6 Plastic coatings323

14.7 Concrete coatings325

14.8 Metallic coatings327

14.9 Methods of metallic coating328

14.10 Behaviour of metallic coatings329

14.11 References335

14.12 Bibliography335

15 Corrosion properties of some metallic materials336

15.1 Plain carbon and low alloy steels338

15.2 Stainless steels341

15.3 Cast irons347

15.4 Aluminium and its alloys348

15.5 Copper and its alloys351

15.6 Titanium356

15.7 Nickel and its alloys361

15.8 Applications in water systems364

15.9 Selection of materials371

15.10 References373

15.11 Bibliography373

16 Cathodic and anodic protection375

16.1 Theoretical basis375

16.2 Sacrificial anode design380

16.3 Sacrificial anode applications387

16.4 Impressed current protection393

16.5 Impressed current applications395

16.6 Anodic protection403

16.7 References404

16.8 Bibliography405

17 Corrosion at elevated temperatures406

17.1 Metal oxides408

17.2 Breakaway corrosion413

17.3 Growth of oxide films416

17.4 Oxidation of alloys419

17.5 Hot corrosion423

17.6 References426

17.7 Bibliography426

18 Worked examples and problems427

18.1 Worked examples427

18.2 Problems433

index457